Yes,
WebCam Monitor can simultaneously take photos and videos from multiple webcams.
Add both cameras in WebCam Monitor. Select Take Photo and Video recording action from Quick Access for each camera. Using the 'Configure...' button you can adjust the image quality and number of images to capture.
You can capture the photos and videos at a regular interval or on motion detection. Just click the 'Start Monitoring' button from the Quick Access for each camera. You can also add a schedule to start monitoring on both cameras.
Select both cameras while adding a schedule and the type of schedule you want, such as Daily, weekly, etc. When the schedule launches photos and videos will be captured from both webcams.